Statistical Mechanics (PHY 540) Fall 2017

Lectures: Harriman Hall #112, TUTH 8-9:20AM

Office hours: Physics C-140, Tuesdays 10am-12pm

Course Syllabus: (PDF) or (DOC)


Sergey Syritsyn (office C-140)


28 lectures starting Aug 29, TUTH 8-9:20AM, Harriman Hall #112

Lecture Notes

Will be posted online

Office Hours:

Tuesdays 10am-12pm, Physics C-140

TA and Grading

Gongjun Choi (gongjun.choi[at]

Main textbooks

[1] L.Landau and E.Lifshitz, "Statistical Physics, Pt.1", 3rd ed.
[2] K. Huang, "Statistical Mechanics", 2nd ed.
[3] K.Likharev, "Essential Graduate Physics, Part SM", posted online.


Weekly, deadline 1 week after handout
Grades and solutions 1 week after the deadline

Course grading

Homeworks: 25%
Midterm: 25%
Final exam: 50%


Open books Midterm: Oct 10(Tuesday)
Final: Dec 12, 11:15am-1:45pm

1. Introduction and Review of Thermodynamics

Basic notions of statistical physics and thermodynamics: energy, entropy, temperature, work and heat. Thermodynamic potentials and circular diagram. Heat capacity and equation of state. Thermodynamics of ideal gas. Systems with variable number of particles and chemical potential.

2.Principles of Physical Statistics

Statistical ensembles and ergodicity. Probability, probability density, and density matrix. Microcanonical ensemble and the basic statistical hypothesis. Definition of entropy and relation to information. Canonical ensemble and the Gibbs distribution. Statistics of quantum oscillator, photons and blackbody radiation, phonons and heat capacity of crystals lattices. Grand canonical ensemble and distribution. The Boltzmann, Bose and Fermi distributions in systems of independent particles.

3. Ideal and Weakly Interacting Gases.

Thermodynamics of ideal classical gas and the Maxwell distribution. The Gibbs paradox. Quantum ideal gases, the Fermi sea and the Bose-Einstein condensation. Gases with weakly interacting particles.

4.Phase Transitions

First order phase transitions, phase equilibrium, latent heat, critical point, the Gibbs rule. The van der Waals equation. The Clausius-Clapeyron formula. Weak solutions, osmotic pressure. Second order phase transitions, the order parameter, critical exponents. Landau's mean field theory and the Ginsburg criterion. The Ising model, 1D solution via transfer matrix, Onsager's solution for 2D case. Numerical Monte Carlo methods, the Metropolis and the “heatbath” update algorithms. Renormalization group.

5. Fluctuations and Dissipations

Small fluctuations, variance, r.m.s. fluctuation. Fluctuations of energy and the number of particles. Fluctuations of temperature and volume. Time dependence of fluctuations, their correlation and spectral density. The fluctuation-dissipation theorem. Quantum noise and the uncertainty relation. The Einstein-Smoluchowski equation, the Fokker-Planck equation.

6. Elements of Kinetics

The Liouville theorem; the Boltzmann equation; the relaxation time approximation. Conduction of degenerate Fermi gas, electrochemical potential, thermoelectric effects, the Onsager reciprocal relations.


  • (Oct 1) The midterm exam has been moved to Oct 10(Tue). TA (Gongjun Choi) will distribute the graded works on Oct 12(Thu) and explain solutions.

Lecture Notes

  1. Thermodynamics 1 (pages 1-6)
  2. Thermodynamics 2 (pages 7-14)
  3. Principles of Statistics 1 (pages 1-10)
  4. Principles of Statistics 2 (pages 11-22)
  5. Classical, Fermi, Bose gases 1 (pages 1-9)
  6. Classical, Fermi, Bose gases 2 (pages 10-16)
  7. Phase transitions 1 (pages 1-12)
  8. Phase transitions 2 (pages 13-20)
  9. Fluctuations (pages 1-11)
  10. Kinetics 1 (pages 1-15)


  1. Homework 1(due Thursday Sep 14) -- Solutions
  2. Homework 2(due Thursday Sep 21) -- Solutions
  3. Homework 3(due Thursday Sep 28) -- Solutions
  4. Homework 4(due Tuesday Oct 17 in class) -- Solutions
  5. Homework 5(due Tuesday Oct 24 in class) -- Solutions
  6. Homework 6(due Tuesday Oct 31 in class) -- Solutions
  7. Homework 7(due Thursday Oct 9 in class) --Solutions
  8. Homework 8(due Thursday Oct 16 in class) --Solutions
  9. Homework 9(due Thursday Oct 30 in class) --Solutions
  10. Homework 10(due Thursday Dec 7 in class) --Solutions


  1. Midterm (March 24) --Solutions
  2. Final (December 12) --Solutions